baby ducks are NOT waterproof
their oil glands take a bit to develop, when they are raised by mom, they can swim and play in the
water, because mom will preen her own oil gland and then preen her babies- giving them waterproof protection from herself till their own glands catch up
if they are not raised with mom- they can not waterproof themselves
if they are being raised by mom (it sounds like they are) maybe he was being a stinker and missed his mom preening time?
how old are we talking here?