My first question would have to be which variety of Barley did she grow? There are already modified 6 row barley varieties that were modified for their allopathic tendencies if it were one of these varieties then perhaps her observations are dead on.
Most barley, while being slightly allopathic in nature does not produce allopathy that persists over time.
I've never found any grass or vegetable type plant that has a persistent allopathy, unlike
trees, which do have persisting allopathic compounds they exude, one of the most famous of these is the Black Walnut.
Redhawk