Simple
answer -- whatever makes the most biomass.
The chemical reaction in a biodigester is C6H12O6 ----> 3CH4 + 3CO2.
Or if you want to put it into words, every molecule of carbohydrate breaks down into equal parts methane and
carbon dioxide. So to get more methane, you have to have more biomass going in.
What's that you say? Biomass is more than carbohydrate, there's protein and fats, and besides there's different types of carbohydrate and.....
In the famous words of W. C. Fields, "go away kid, you bother me". There's too many other things to do in life than to take inventory of all the chemical reactions going on in a biodigester. The one reaction above describes 97% of everything you need to know about your bioreactor. So whatever biomass you can shove into the bioreactor, give it a little time and you will get your methane.