Light doesn't pass through cob very well
(sorry, cheap shot, but I couldn't resist)
There is a sort of double walled plastic stuff that comes in big rolls. Made for greenhouses.
Based on what little I know, I would think that single pane would work fine if you have a rocket mass heater in your greenhouse.
Oehler's greenhouse was single paned and full of holes to the outside and he had tomatoes in december in north idaho.