Bryant RedHawk wrote:first off, the grounds are fine enough that they will turn to ash long before they would become char, they are far more valuable as compost additions or simply added to a garden bed as part of a mulch layer.
Redhawk
^^ Affirmed!^^
This would the primary concern. There just isn't enough structure in a small fleck of coffee that would remain after it's been charred. It would simply turn to dust.
Biochar is a hotel for microbes. They move into the nooks and crannies and take up residence. With a chunk of wood, much of that structure remains after charring, and thus, many rooms are left in the hotel for the microbes to live.
Coffee grounds then serve as the food source for those microbes. There's not enough pore space in a tiny charred chunk of coffee to make a hotel for the microbes. It's better to just let them decompose the coffee and have a hearty meal.
"The rule of no realm is mine. But all worthy things that are in peril as the world now stands, these are my care. And for my part, I shall not wholly fail in my task if anything that passes through this night can still grow fairer or bear fruit and flower again in days to come. For I too am a steward. Did you not know?" Gandolf