Hi Tatton,
I would not pack slip-straw (light-straw-clay) into a cavity that has a very low vapor permeable barrier on one side--that's asking for the straw to begin decomposing because the mix can't dry out quickly enough.
A 12" wide slip-straw wall is pretty much the maximum LSC wall depth for this reason, and the walls are left to dry from both sides until ready for plastering, usually at least three months of warm, dry summer conditions, and more often eight-to-ten months later in areas with damp winters and less than super dry summers.
Theoretically, a 6" wall will dry to one side only (the interior) since the plywood (presumably 1/2"? CDX ) has a very low vapor permeance--it'll allow
water vapor to escape, but probably not fast enough to prevent moist, warm conditions from decomposing the straw. You could drill a bunch of holes in the plywood to make it more vapor permeable, but there's a limit to that as the plywood is probably the material that supplies shear (out-of-plane force resistance) for the structure. Too many holes and it won't hold up as expected.
Unless someone on this forum has done what you propose in a climate similar to yours and has checked to see that in fact the slip-straw survived without signs of decomposition...I'd look for a different insulation here. Unless you want to take a chance and possibly have a very costly do-over on your hands.
Jim Reiland
Many Hands Builders