My guestimate is that applied fertilizers are like a huge shot of nutrients, so much so that much of it goes unused and is washed away. But I would imagine that any N fixers put out a sustained level of N that could be utilized immediately, effectively giving your plants *more* nitrogen than by fertilizing (unless you fertilized near constantly). And I would second Rebeccas question/suggestion that any remaining N would not get far beyond the
root structure of your legumes before being utilized. I would be much more concerned about stuff coming the other way.
I would think your biggest risk is that the corn is Roundup Ready and that they hose everything down with Roundup regularly to control "weeds". My concern is that it would end up "controlling" anything you're trying to grow as well. That and you might not be able to save seed from any corn/beans/whatever else you're growing. That said, it all depends on exactly what "spray" means.
I think your best starting point is to have a friendly visit with each of your direct neighbors and ask them (politely) about their methods - especially if there are ones uphill from your property. Then, once you know what's going on, you can try to mitigate from there if necessary.