When you go about filling a mold with cob, chances are pretty good that you will cross over into making "rammed earth" as distinguished from "cob". It's not a massive distinction, in that a mix that will work for cob will almost certainly work for rammed earth (the inverse is not quite as true). Thing is, once you start pushing your material down into that mold, you are no longer "cobbing" so much as "ramming".
And I can tell you that having built a wooden box, with a wooden sacrificial burn tube mold that went in the box, and loaded it up with my clay/sand/perlite mix (I was going for straight rammed earth with this, so no
straw as you would plan for cob, packed that stuff down in there to be sure it filled all the gaps and so on, once it had a couple of days to dry, so that the exposed top surface looked to be dry, I had no problems removing the wood from the earth mixture.
Your mileage may vary, of
course, but here's one report of doing pretty much what you are talking about, with no problems removing the mold.
My problems have come later, as my material is short on clay and crumbling much too easily.