posted 11 years ago
If you engineer the wall/roof to carry the load, you could use cob, adobe, fired-brick or stone. Bales are really big (and slightly squishy) masonry. Use masonry designs for bales. If you want to use straw for an A-frame, put it in an appropriate form: thatch, panels, mats, strawjet columns, loose fill (light straw clay) etc.
If you want high R-values in a roof but want to use natural and/or sustainable material, there are lighter options.
Straw bale vaults use the weight of the bale, instead of fighting it. Gothic arch vaults look similar to an A-frame.