I think you will mess it up if you do that.
We want sharp corners in a
rocket stove, because we want
turbulent flow. You start filling in sharp corners and rounding edges, and the flow is going to become more laminar. If it does that, then unburned gases will travel further up the chimney where they may cool to the point that they don't burn at all, just put out more creosote and smoke. And with laminar flow, it won't roar, so you won't have a "rocket" stove.