Hello David,
I hope others will have a chance to share with you their thoughts, but as I gave a quick scan of your design, I had more questions than good advice. I don't translate "words" well into three dimensional shapes so I will admit to not really understanding the actual design of your stove, as it does not seem to me to be of the standard
RMH format.
What I can share, and many of us here are writing all too often... Just because it is on the web in words, or
video, does not make it a good idea, concept or design...
Portland (OPC) has no place in stove, kiln or masonry heater design. It doesn't even need to be in the foundational elements, but definitely does not belong in any of the interstitial or dermal component matrix.
Bentonite clays are too expansive to use in the design matrix of combustion chambers.
I am not clear on, "If I had access to clay in bulk I would just mound it all around the barrel to seal it..."
If you have access to a type s mortar, thens I don't really know of any area that doesn't also supply clay...even really inexpensive clay just out of the ground. Almost all over North America there clay, often good clays just found in roadside ditches, either naturally harvested or bag as simple processed fire clays. If you can get 50 lb bag of ground fire clay then that is all you really need unless I am missing something that others will catch about your design.
PS One more thing - I see some articles about building pizza ovens that talk about using portand where you have to wait about 3 weeks before first heat. As it is now past mid-November in Vermont, this just isn't an option. I need something that will be ready in 2 or three days if possible, if just to get me through winter, and then in spring I can do something better.
Please share the link for, "pizza ovens that talk about using portland cement," for my own understanding, I would like to see what someone may be trying to suggest.
I will share again, just because someone is doing something and making a video about it, does not make it a good idea. OPC is not a material (nor industry behind it) to support or use for such an application. I too live in Vermont, and it can be frustrating to have seasons sometimes, but just like I can't expect to plant a garden now, neither can I do certain other activities...like building an outdoor clay oven...or at least...not with more effort than it is worth.
If you can provide photo or drawings of your design I know that wil help everyone in giving their opinions and assistance.
Hope that helps some,