Like most of you I love volunteers or self-seeded plants. I almost always get volunteers from red Hopi amaranth (Amaranthus cruentus), vine spinach or basella (Basella rubra) , quail grass (Celosia argentea), rice beans (vigna umbellata)spider wisp (Cleome gyandra), purslane (Portulaca oleracae), orach (Atriplex hortensis), shiso (Perilla fructans), and hyacinth beans (Lablab purpureus), as well as some of the ones others have mentioned. The edge of the
compost piles is always a rich zone for free plants. One of the great things about self-seeders is they select for success in your conditions and they decide when is a good time to sprout, saving you some guesswork.