Like the previous responses, I tend to think of spiders in terms of their food items. We have quite a few but I don't kill them (though I would dispose of a dangerous one).
If you're determined to get rid of spiders: Have you tried using a shop vac with a wand to just do all the edges, corners, etc. in your greenhouse? I don't think anything is going to permanently do away with spiders, but shop vaccing would get lots and would have the added advantage of cleaning things out, probably getting a lot of other bugs, too. Then you could
compost all that nice protein.
The other thought that comes is diatomaceous earth. Arachnids have exoskeletons and should be susceptible to it.