Good to hear that the building inspectors are open to alternative building.
If you don't have one, either get a copy of the IBC or go to the library for one you can read and make notes from.
Bottles are not going to be analogous to double pane windows because you won't have argon or an other gas contained within the double bottles.
They will however be able to offer a higher R-value than single pane windows and that can be improved with insulation as you do the construction.
You can use the Cord
wood double wall construction technique and have a minimum R-30 wall, This technique uses shorter wood sections and is easier to construct since you don't have to put any insulation medium in the middle of the chord wood wall, between layers of mortar.
The double wall method also gives you easy chases for all wiring and plumbing
should you want to do that as you build. (It has been used in Upper Mich. and that original house with a
wood burning stove for heat uses 2 chords for an entire winter, not bad at all).