In general, lithium batteries are always charged with what is called a "Battery Management System" or "BMS" for short. That's because lithium batteries need to be charged very, very carefully under strict control. Otherwise, some can rupture, catch of fire, and have killed people! Airplanes have crashed because of lithium battery fires. I suspect that third connection is for monitoring the charge being given. Don't just try to jumper some 12V charger wires to it and expect it to work properly.
Please don't try to actually use/charge this battery until you've contacted the manufacturer to find out exactly HOW this battery
should be charged.