Probably we are missing on the construction details that limit the ventilation. Does the greenhouse have any openings or is entry only from the house?
Is this a manufactured unit? or something you are constructing yourself? General expectation is that a manufacturer will have designs for ventilation.
There are many examples in this forum of storing the excess heat for later use. If you are going to use a vent fan it can be set up to blow the hot air down a pipe and under the floor of the greenhouse then exit on the other end while another
underground pipe brings cool air into the greenhouse. Consider also an insulating cover that can be rolled out over the top for shade when there is too much sun and all the way over the front to keep heat in when there is no sun.