Are you able to get your soil tested? That would be the best way to see which minerals are missing. If calcium is low, you could try plants that accumulate calcium (dynamic accumulators). The following plants take up calcium and store it in their leaves:
German Chamomile (C. nobile) (also accumulates K and P)
Silverweed (P. anserina) also accumulates K and Cu
Comfrey (Symphytum spp.) (one of the best, accumulates Ca, K, P, Cu, Fe, Mg
Nettle (U. dioica) (Ca, K, S, Cu, Fe, Na)
(info from Edible Forest Gardens by Dave Jacke)
when the plants die down for the winter, or you cut them back as mulch, you keep the calcium cycling through your soil. Holding the calcium in plant tissue prevents it from leaching out of the soil. If you want an all purpose plant to keep fertility high, comfrey is my choice, but do your research, as it is dispersive and opportunistic. The russian comfrey has been reported to be less feisty.
Best of luck!