Great thread. I think that how organic mulches turn into compost is one of the many reasons they are infinitely better than plastic.
I have spread a lot of woodchips (hundreds of yards) on my gardens and food forests, but seems like soil microbiologists (James White, Elaine Ingham, many others I have read or heard on podcasts) are getting more and more evidence that the best mulch is a living plant. All plants produce exudates to feed microbes which in return provide plant available nutrients. At least 30% of all plant sugars produced go to microbes, with up to 50% seasonally. When we chop and drop a weed, the greens provide shade and food for microbes, and the roots decompose and leave corridors of compost for future roots of plants we want to grow.
So I have come to only pull weeds when seeding or planting starts, with the exception of really aggressive spreaders like grasses, ivy and mint which I do try to get roots and all. Otherwise, everything just gets cut back with my brush cutter in late spring just before fire season. I use a sickle for right around trees and plants I want to keep. I leave most of it on the ground, ideally covering planting bed soil. I do move some to compost piles because piles of drying cut grass upwind in fire weather is a risk to our house.
If I have bare ground in the winter for some reason, I will mulch with woodchips. I also use them in my sunken pathways between hugel beds. If a have a future garden or tree planting spot that has minimal soil to grow plants to get the soil sugar pump primed in the first place, I will spread woodchips to decompose and build organic matter. I use woodchips or woody debris around trees to get soil fungi a boost, but have leaned into spreading it less and piling it more since reading Michael Phillips’ “Holistic Orchard.” I have seen enough benefit and little perceptible harm in using conifer that I don’t worry too
much about it, but I will take all the alder I can get.
I think rocks make sense in very dry climates. Both plants and rocks help provide much more surface area for dew formation. If woody debris is broken down below 1ft/30cm, it generally gets enough soil contact to stay moist enough in the wet season here to inoculate with fire retardant fungi. In really dry climates though, it may just oxidize like was mentioned in a post above. Crushing this organic matter to the ground or eating it and depositing it as manure that then gets spread by smaller animals is a big reason why large herbivores moving frequently are so important to savanna and prairie ecosystems, and are essential to preventing their desertification.