Thanks all for the info & advice.
I'm planning something like this system (only possibly with a smaller bin)
https://permaculturenews.org/2018/12/21/how-to-make-a-compost-toilet/ . So the bin will drain away moisture through a grill near the base, and be ventilated top, base and with perforated pipes on the inside so the process will be aerobic, though obviously not as much air as a compost heap. The only difference is we want to separate the urine off as with it being for holiday guests keeping smell to a minimum is important, but I guess will still need to add some moisture to prevent everything getting too dry.
Maybe the best way to go is to trial with smaller 80/110L bins and if we find they're not composting down sufficiently on their own we do as Bob suggests and transfer the contents to a larger compost heap to finish the process off.