Welcome to permies Lisa
How unripe are we talking?
Really green, like much less than full-sized, could be pretty unpalatable, but full-sized unripe, make good chutney and are ideal for jelly.
Is there much sweetness in the fruit yet? If biting into one makes you screw your face up in disgust, I wouldn't suggest using them. And I don't mean the "oh man, that's sour, give me some more" of crabapples, more the "my tummy hurts" end of the scale.
I haven't made
apple cider vinegar from unripe apples, but maybe that would work. This
vinegar thread might help.