I think I see what you are getting at here. Offsetting has a particular meaning in carbon accounting (and has been described as like buying medieval indulgences), but I don't think this is what you are talking about.
Basically, it's simply not how carbon intensity is calculated. There are range estimates and means calculated for production of various foodstuffs under different conditions, typically including all known inputs, plus transport, wastage and so on. There is a discussion on another
thread for how to calculate carbon sequestration under various agricultural techniques, including food forestry, but you also need to take inputs into account. I think you would struggle to find a food that is carbon negative, although with food forests we can move in that direction. A nut from your home garden may well be, but we are not at the point of accurate measurement because we don't yet have reliable, comparable means of comparing carbon sequestration in soils.
The same is true for natural gas being burned, natural gas in leaks (although it's starting to look like this has been grossly underestimated, but we know how much is being sold), and estimates for biofuels, including wood burning, which creates its own environmental problems (at a global level chopping of fuel wood is a major source of deforestation, but different issues apply in small-scale coppice; both include issues of soil depletion and so on). Wood heating is not "good": on a small scale it can be less problematic than using fossil fuels, but it should
not be considered a renewable resource, especially on a large scale. Burning wood is not a negative on the ledger: it's theoretically neutral in a perfect situation, which you are unlikely to find. It may reduce the amount of fossil fuels being burned, but you have to take other factors into account.