Being a brewer, I can say that malted barley does indeed contain amylase, both alpha-amylase and beta-amylase. If you have a
local home-brew shop, pick up a small amount of grain and mill it fresh. 6-row barley has much more diastatic power (more enzymes and ability to convert starch) than 2-row. Heat is necessary to activate these enzymes and get them to chew on starch chains, approximately 142-152f for beta amylase and 148-160f for alpha amylase, with a small temperature window where both are active. Home-brew shops usually also have a liquid amylase ready to use if you don't want to fuss with milling grain and applying heat for 30-45 minutes to get conversion.