If we could find a way to heat greenhouses all winter so they never froze and do it for little money, we could solve the worlds hunger problems. I have been working on this issue for many years. I have a 20' x 30' hoop house and I can grow food all winter, but not much when it is wicked cold and the days are really short.
A single layer of black painted tin on the south side will increase the
solar gain a little. I use black barrels inside my greenhouse that are filled with a non-toxic antifreeze. The barrels get warmed whenever it is sunny and they hold heat for night time heating. Unfortunately, if there are many days with no sun, it will get cold in the greenhouse.
I suggest looking at plants for the winter that are very hardy. Elliot Coleman has a book out that is about winter time greenhouse use, and I suggest you get a copy and see what he is doing.
Bob