Thomas, you are correct in your understanding of my question. Stepping back just a bit I spent the winter as I often do, staring at my wood stove and thinking about the heat going out the chimney. I kept thinking about how to recover some of that heat before it leaves. The addition of an additional compartment between the stove and the flue seemed like it would help. I am not trying to create a rocket stove heater, just make what I have more efficient. Since I don't consider myself the sharpest knife in the drawer, I guessed someone here has already had the idea and tried it.
If that second chamber had more baffles and mass will that help?