Neo Ceram / ceramic glass is the stuff that holds up best.
It can sometimes be found in stove doors, or the tops of "glass" topped cooking stoves (electric kitchen stoves).
We've had mixed results with Pyrex or similar tempered glass. Some people use it for lids, in areas a bit back from the worst heat of the fire. Some people have had Pyrex in the fire walls that shattered rather spectactularly within a few minutes of lighting their first fire.
Matt Walker's video (broaudio on youtube) shows one innovative way to re-use a small woodstove door.
For those who care how the heater works, not just how it looks:
Be aware that glass is generally not as good an insulator as the more typical brick-and-perlite or brick-and-insulation we use to build the fire box.
Glass inserts may cause poorer performance or a dirty burn.
Introducing a thin glass-walled section to the firebox may also introduce cracks / stress / air leaks, and will require a higher level of skill than typical
RMH construction.
(doubling up to two or three layers of glass could reduce the heat shock and potential heat loss, but only adds to the skill needed to ensure heat-resistant, airtight, expansion-jointed construction).
The original developer, Ianto Evans, consistently said, "If you want to watch a fire TV, light a candle."
We've had some folks build a small Rumford fireplace in next to their
RMH, for occasional "fire TV" viewing pleasure, while still being able to shut down the fireplace shutoff damper and run the heating on the more efficient RMH.
-Erica