I wouldn't use it, for a few reasons:
1. Environmental footprint of manufacture + transport...the stuff's hardly a poster child for earth friendly materials.
2. Offgassing into living space. Most PU for direct application (as well as adhesives like Gorilla Glue) contains methylene diphenyl diisocyanate, which has all sorts of toxic effects, many of which are known to the state of California.
3. Breakdown under UV exposure, as mentioned above.
4. The stuff traps
water amazingly well (lesson learned the hard way when I used it as a teenager to fill rusted quarter panels on my beater first car). This makes me doubt that it's breathable, which is a red flag for something that will be part of the building fabric.
According to this article there are some possible green alternatives:
https://www.scientificamerican.com/article/better-home-insulation-needed-to-ward-off-chemical-exposure/ I have no idea about pricing, availability or long-term performance on these but they look attractive at first glance.