Hi Malcolm.
I would suggest you refer to your soil test. If you haven't gotten one yet, that really
should be your first step.
There is far more to soil than its pH. A soil test will tell you that, and having that information will also help those of us on this site make suggestions better suited to your situation.
As to the wood ash, do be aware that this is the same stuff that was leached to produce lye for soapmaking. You want to be careful, if storing it in quantity, to make sure it's not going to get wet and leach into something you'd rather not have soaked in lye.
The charcoal is something else. If you were making
biochar, I would inspect the little pieces to check the porosity, especially if I had a microscope or suitably powerful hand magnifier. If they don't smell, and/or if they clink almost musically when you knock pieces together, you could probably put those pieces, whole or crushed, in a healthy, active
compost pile, where they will act as little mobile homes for soil microbiota.
Bryant RedHawk has no fewer than two excellent threads on soil building and soil science on this site. If you have some time, read over them. They are a wealth of information, but presented in a very comprehensible manner.
So let us know how it goes. Good luck!
-CK
A human being should be able to change a diaper, plan an invasion, butcher a hog, conn a ship, design a building, write a sonnet, balance accounts, build a wall, set a bone, comfort the dying, take orders, give orders, cooperate, act alone, solve equations, analyze a new problem, pitch manure, program a computer, cook a tasty meal, fight efficiently, die gallantly. Specialization is for insects.
-Robert A. Heinlein