Nice score! This looks to be a sweet little system.
Do you have only 1 collector?
It looks like you have an 80 gal tank, this would typically have 3 collectors, at least 1 sq ft/gal is the rule I was taught. I don't know what your heat exchanger is rated for, so check that before hooking up any more panels.
I would not use the solar as a pre-heater to your standard 40? gal water heater, but would tie them in parallel to prevent low temps in the solar tank from growing Legionella bacteria. It looks like you have a bronze circulator for hydronic heating and a smaller one for the panel so you can pull the big pump if you are going to use this for DHW.
Run propylene glycol in a mixture appropriate to your climate. Since glycol degrades thermal performance, you want to use as little as possible.
To clean hard water deposits; fill a 5 gal
bucket with white vinegar and water, hook up a hose to the inlet and place the bucket under the outlet, run the pump for 1-2 hours and all calcite will be dislodged. Collectors can be cleaned in the same manner. I would probably just flush the tank really well.
You may want to invest in a modern controller like the DS.
Good luck.