Hi Caleb,
I share the general concern about plastics, however from a slightly different angle.
Not all plastics are the same: You can install a greywater system, like the laundry-to-landscape system, using HDPE (high density polyethylene) which is a more benign type of plastic than PVC- a more toxic variety.
Gravity flow systems can use ABS instead of PVC.
It's hard to totally avoid plastic nowadays: In our social context, where drinking water often is plumbed in plastic, food is packaged in plastic, most people drink or eat out of plastic (at least on occasion), using plastic pipes in a greywater system is a very small amount of potential exposure through the food system compared to these other ways. If the greywater pipes are kept of out of the sun and the water is inside the pipe a short amount of time (it's just flowing through) little chemicals would be leached out. I do not know about the fate of chemical compounds that leach from plastic entering an aerobic soil environment or how much they may be absorbed by plants, but I assume the amount is negligible compared with using plastic directly with drinking water, like drinking out of a plastic cup in a restaurant. Also, most any irrigation systems or hoses we use to irrigate contains plastics or other potentially harmful materials.
Making plastic is toxic: From my perspective, the main issue with using plastic in a greywater system lies in the problems with manufacturing plastic. Making plastic, particularly PVC, is a toxic and environmentally destructive industry. The manufacturing plants are very harmful to the health of people who live near them, an environmental justice issue. We
should try to minimize and avoid plastic, PVC in particular, as much as we can. Some of this can be done with the design of the system, by locating plants to be irrigated with greywater as close to the greywater source as possible.
Perhaps bamboo: Unfortunately using metal pipe in a greywater system is not practical for most people. It's expensive and harder to work with. If anyone has metal pipe made for water it would be fine to try to
reuse it though. I think the most practical option is using the less-bad types of plastics, like HDPE. Or perhaps using bamboo. I haven't done it myself, but bamboo has been used for water pipes around the world, though the longevity won't be as long as with plastic or metals. I'd love to hear from people who've tried using bamboo for greywater piping.
No pipe options: Art Ludwig has a good alternative to pipe for rural situations (definitely not up to any US code), using cement lined trenches that branch water to plants. I did a quick image search and couldn't find it on-line, but there are images in his book "Create an Oasis with Greywater".