In my experience
wood buildings are easy
enough to build another door and green houses don't need to be square, but they just take custom built for the odd angles. Not sure if you have a a wood house or something else.
Consider the price you will pay for the
project. It may be more than you'd expect. Also consider how you can reduce your heat loss or useother alternative energies. Like, wood energy for heating, if you can get a supply.
Rocket mass heaters are supposed to be good and cheap. When using
solar, consider your daylight calculators. Here solar panels can be expected to do only up to 1/10th of our needs. Wind and wood and others on the other hand are very promising. Proper insulation also will reduce your energy needs. You might be sorted how non-insulating things like brick and cement can be and how much of a difference little holes in insulation matter.
Check out this I put together for cheap energy saving tricks.
https://permies.com/t/62284/ways-save-winter-heating#531358
Good luck!