Jack Slaggert wrote: As wood ash is radially available and costless
You might want to try experimenting with the locally available wood ash, wetting it and forming can form a geopolymer that will harden to a ceramic with relatively low heat You could make insinuative material by foaming or adding sawdust that will burn out and leave voids.
Keep in mind that you either want to make out of brick shapes or casting multiple pieces otherwise a monolithic casting will likely crack in places where you don't want it to, due to wide temperature differences and expansion rates through the rocket core.
Here is a video from the awesome Primitive Technology youtube channel where he makes a pot from woodash.