nitrogen deficiency is yellowing of the leaves, iron is yellowing of the leaves with green veins. The brown spots are not related.
Where i live nobody seems to know what im talking about when I say ferrous sulfate, so I had to resort to grinding up iron vitamin tablets and dissolving them with vinegar before mixing with allot of
water. It saved my raspberry's twice and I did my fruit
trees before they had a chance to show signs.
grinding up the iron tablet is something you can do tonight, try tomorrow and thee the results in 3 days, if you can get the sulfate that would be great and need less reapplication.