The simple explanation? Calcium is a +2 ion, so it has two arms reaching out, able to grab some negative charge. It can pull things together like a parent reining in toddler twins headed in different directions. Sodium can't do this. It is only a +1 ion, so if it grabs onto something, it just goes along for the ride wherever the negative charge was headed.
Clay particles that are so light that it takes them a very long time to settle out. But once a few particles get agglomerated together, courtesy of the calcium ions, they are big enough to settle.
Can you really tell me that we aren't dealing with suspicious baked goods? And then there is this tiny ad: