I am somewhat amazed by the quick and useful answers to most questions. Thomas has apparently given this so much more thought than i have.
I agree, with the point of tackling the easiest to handle first. Since this is done individually by each neighbors knowing when they will want to dispose of waste might be a problem with picking it up. If it is possible and you wouldn't mind picking it up, perhaps you could get the neighbors to dedicate some items (I am thinking they wouldn't want to have to invest money in a can) which you might empty weekly.
Compost the waste in one of many ways, worm, compost pile or best yet but expensive is the bio gas production (india has that down to a science you might look into that). Now by each method you have left over fertilizer, use it or sell it back to neighbors or better yet trade them fertilizer for garbage waste and you can stop picking it up. It is possible you might have to deliver the first bucket of compost back to them to try out ...we, who use that stuff, are addicted to it...the crack of the gardener.
I think with a bit of luck the locals will see that it is to their advantage to not only get cleaner air but to gain the benefits of the end product...people being a bit on the lazy side will likely figure out that they could compost the materials themselves
Do they actually collect the precious metals from burning old tv sets or whatever? If they do not then perhaps knowledge of the existence of these metals in the units would make them more thoughtful about how they get rid of them. I am sorry but i have no solution there. It is my thought that with each step in better air they will think better of it and more ideas will come. Start small and work your way up.
I admit thomas is more of an expert when it comes to wastes, I just wanted to share my thoughts hoping you can find a gem or two among the garbage you can use.