Hi Jason; Welcome to Permies!
Well there is a big difference between a rocket stove (meant for cooking) and a rocket mass heater (meant for heating)
Which were you interested in?
With rocket mass heaters. Peter Bergs Batch box design would produce the hottest temperatures. Here is a link to his site
http://batchrocket.eu/en/
Ceramic boards and ceramic fiber blanket in your core and riser, are quickly becoming the builders material's of choice.
These are proven technology for obtaining the most efficient hottest burns.
Many other methods have been tried. You-tube is very popular for folks to showcase their ideas and builds.
Not all of them last very long. Sometimes they fail ...We call them "Flaming units of death" only rarely do we hear about this. Most folks are too embarrassed and you never hear about their project again.
Check out the rocket mass heater forum here at Permies. Check out Peter Bergs site. And another site run by a good friend
http://donkey32.proboards.com/ also full of great information.
Find a copy of The Rocket Mass Heater Builders Guide, its full of build information.
Come back with all your new questions after you check things out.