I use cedar branches and slash for my driveway, to keep traction in the rainy season. It works good, but its not a permanent solution. If your cedar boards are heavy on heart
wood, they will stay on the ground for a good ten years and work for you. They might split, but they'll still be okay for walking on. Any allelopathic effect will go away in the first year or so, and as for pollution from the stain, well, I'm sure you can think of other forms of pollution present on your property. You have stain on your porch, right? But the garden down-hill from there seems to be doing okay. (assuming you have a porch. I'm sure some people do.)
Regarding allelopathy, cedar is demonized a lot on these boards, but chemical warfare is very very common in the vegetable kingdom and can't really be avoided. I would feel worse about erosion along a path than I did about putting cedar wood down on it.
But putting them on the ground might not be the highest and best use for the boards. If you wanted to make a
chicken coup, they would probably be functional. If you like snaring
rabbits, you could use them as part of an artificial warren.
Splinters? If you are walking around barefoot you will get stuck with something eventually.