Firstly there is a type of hive with straigh walls its called the tanzanean top bar hive .
Secondly the reason for the slope is that it matches the natural shape of the comb produced by the bees , ok the bees dont do straight but it comes close and this means that there are less air spaces for the bees to have to keep warm or full of bee scent . So its more efficient and less stressfull for the bees . Thats the idea anyway
David
Living in Anjou , France,
For the many not for the few
http://www.permies.com/t/80/31583/projects/Permie-Pennies-France#330873