Hi, Rosa, under olives in my region grow all sorts of wild allium spp, so I guess you could plant those, wild carrots grow well so you could plant carrots, mints (but they are a bit invasive some say), herbs grow well, I guess you could plant spinach ( I prefer planting spinach in late summer so it doesen't go to seed and I collect leafs all winter round), and in future think about climbers they love to grow on my olive trees. rosa canina grows well close to my olives, and even rubus spp grow well under olives maybe you could look into small shrubs that give berries, because some berries are really exuberant. it depends a lot on how big the olive trees are.
Don't worry for coffee grounds they won't have done any damage on the contrary, and if you put
compost and wormcastings it will be great.