Nick Kitchener wrote:Discovering that the amount of methanol involved can be very significant left me feeling rather disappointed.
Am I wrong in my views on biodiesel? Has technology advanced? Is there a process where the other main ingredients can be readily manufactured on a homestead (like ethanol)?
Your comments would be very much appreciated 
Hi Nick,
I share your concern.
Biodiesel is term used for the fuel use of methyl esters - a product of a reaction involving methanol, fats or oil, and a catalyst typically potassium or sodium hydroxide (KOH or NaOH). Methanol is typically made as a byproduct of natural gas - often a byproduct of the petroleum industry and comes from places like Iran, Qatar, Trinidad, Equatorial Guinea , and Russia. KOH and NaOH typicaly comes from China these days.
A typical biodiesel reaction uses 22% by volume of the fat or oil to be converted - not insignificant.
Ethyl esters (made using ethanol) are another possible fuel source but the processes required to produce anhydrous ethanol (without water) are a bit daunting for homescale. The alcohol (methanol or ethanol) needs to be about 99.5% pure or better to make the reaction worthwhile. The amount of ethanol required to make ethyl esters is also greater, which is partly why it's not cost competitive commercially.
To my knowledge, there is no energy without impact - not wind, solar, hydro and certainly not biofuels. The original biofuel that powered people and farms was hay for farm animals - also not without impact but arguably more sustainable that solar, wind, hydro, and biodiesel or ethanol. I think the more we can reduce our need to commute, shop, and recreate far away from our homes, the better our lives will become. Call me a Luddite!
Although I garden daily, home brewed beer for 10 years, and my wife has been making all of our bread for about 10 years - I have never homebrewed biodiesel. I have worked with five commercial biodiesel producers so have been able to run my vehicle on B100 for the last 14 years. I'll admit that if and when I don't have access to commercial biodiesel, I have no intention of homebrewing myself - just not into it. I'd happily buy it or trade for it with someone who did though!