Hi Fianou, I don't know what cane is, but there are many different plants that can be used in cob.
I've just checked in my copy of the Hand Sculpted House and I'll summarize what Evans Smith and Smiley say aobut straw
The functions of straw in cob are to strengthen it, and to provide insulation, )the air spaces trapped inside the straw.
You want tensile and shear strength in the cob, and the straw is what provides these qualities, but to do so, it must not be rotten, it needs to be strong, and in long pieces.
There is a difference between straw with hay. Straw is cut after the grain has ripened and is harvested, straw is sort of biologically inert. Hay is cut while green and nutritions, making it of interest to insects and easier to decompose.
To check the strength of what ever straw you are considering, take a single piece and try bending and pulling it. You do not want it to be brittle. Then take 5 good pieces and put them all together and try to break them by pulling, good straw in group of five will be impossible to break in a tug of war.
The best straw will be fresh and dry, or have been stored in absolutely dry conditions.
Other plants can be used, if you can't get straw from grain plants. Oat straw and rye straws are all good in cob, barley straw can be brittle. Rye grass and canary grass are strong and flexible but are hard to work with.
Kinds of straw to avoid : alfalfa hemp millet milo buckwheat soybean sorgum
flax and corn.
They also say dry hay is better than wet or rotted straw, and that traditional cobbers use what ever is available: rushes, and tussock for example.
So, about the cane: is it long and strong? will the clay stick to it, so that it will mix in and hold things together? What are your other options? The plant fiber of what ever kind you use has very important functions, and it is not temporary, rotting out over time. Old cob buildings have had sound fresh appearing straw after 150 years. You can use what ever will provide those functions.
Make some test batches to check what happens when you use cane.
I hope this helps.
Thekla