I think that thatch comes from shallow watering. I could be wrong.
I think I would start a better watering program and ignore the thatch - it will eventually go away. Mechanical de-thatching takes work, $$$ and makes your lawn look like hell until the grass grows back.
There are times where overseeding can help, BUT! I would first want to find out why things aren't growing in that spot right now. What's the use to toss grass seed on a patch of cement? If the lawn is thin in a few places, add some
compost to those spots. It will improve the soil and when the existing grass gets healthier, it will send out rhizomes and produce more grass!