Welcome to permies!
Heres another useful image of water flow
That's an interesting image - where do you get that from?
I'm not experienced in keylines, and suspect if you just started ploughing across the slope rather than up/down you will see some benefit. As I understand it the keyline ploughing is to plough slightly down hill, but towards the high spots so the water stays in the soil longer and spreads rather than going straight to the lowest spots.
I have had a go at annotating your simple contour plan - red dotted is the high spots, blue/green is the natural valleys/low spots and orange is my suggested ploughing directions. Hopefully someone who has studies this more will confirm whether that makes sense!