You are describing the ideal
wood to use for buiding
hugel mounds.
The more "rotten" the wood is the better it will hold water.
Fresh cut wood is not suitable for this, it will not soak up
enough water and is the primary reason so many hugels fail the builders.
The wood in a hugel is not there for providing nutrition to plants as much as it is there to hold water over the long term so the plants have it available in times of draught.
The primary nutrient supplier is the fill that you put around the wood core.
By the way, when wood rots it is the cellulose that rots away first, the lignin is what gives a tree its structure.
Lichen is a bacteria that is in symbiosis with a fungus, these organisms are not usually toxic.
Lichen is one of the primary rock breaking organisms in nature, producing some of the first soil found in rocky areas.
Redhawk