Toby Hemenway recommends stacking compostable materials on top of brush so that there will be both the ample organic material plus the heat from composting to encourage plant growth (and I would add, extend the growing season). If you have a mix of different materials like pictured here, it seems to make sense to time stack it in a way that makes the more available organic material closest to the surface. As the pile ages and shrinks, the pile could still offer most of the same profile to the roots as when it was a new Hugelkulture bed.
If you are doing Hugelkulture and have a mix of materials, would this be the best way to stack them?