Hi John,      Welcome back!
 
 I remember posting my findings somewhere on permies of the high temp homemade bricks I made a while back. If I find it I will include the link.
 
 Donkey over at 
proboards has done a fair amount of building rocket stoves using all natural materials. One that comes to mind is the cyclone 
tiny-house-rocket-mass-heater at Wheaton Labs. He used clay, manure, grog and wood ash I think. 
 
 I just finished tearing apart my Perlite/clay heat riser the other day and it held up very well. It certainly would not have been good in an area that gets any kind of abrasion though.
 I do remember that I found it very helpful to add some fire cement to my homemade bricks as everything else I tried was just too soft or tended to crumble way to easily. 
 Right now those bricks are installed into the back end of my batch box acting as a base for my heat riser 
J -tube-Batch-Box-Conversion
 
 The straw encased in the cob (especially the area closest to the fire) will mostly burn out but in the process leaves voids that can add insulative value. 
 Every batch of clay is different so there won't be one fail safe recipe to follow...only guidelines.
 
 
 I added your thread to the rocket stove forum as well. Perhaps someone there will also be able to help you. 
 
 EDIT- Found a bunch of other stuff but not my own information...oh well.
 
 Found this comment by Donkey using 
charcoal as insulation
 A thorough explanation of Donkeys process as of 2014 of making bricks: 
dear-donkey-master-cob
 and one more by another fellow who explores sodium silicate and other high heat materials: 
diy-refractories
 Others: 
Making Insulative Clay Combustion Chambers
 Primitive Technology