Important considerations to make in trying to decide whether solar hot water can work as a standalone system is as follows:
1) Where is your hot water tank located (indoors or out?). Below freezing temps at night will sap the heat out of all but the most expensive/well insulated tanks. A minimum of 55mm of high density polyurethane insulation is required to reduce overnight heat loss to less than 20 degrees @ 32 degrees outside temp.
2) Water storage tank size. My rule of thumb is 10 gallons of hot water per person using it. This will provide 2 days of showers per person. We limit showers to 2 gallons per person, but once that 2 gallons of hot water comes out - 2 gallons of cold goes into the tank to replace it and maintain pressure - tank temps will drop dramatically after half of the hot water is used and replaced with cold. Using a mixing valve and low flow
shower features will help you sip hot water thus making it last longer during periods of poor sunlight. A 40 gallon tank managed properly works very well for my family of 4. If we had six trying to use it - it would really be tough.
3) Secondary heating element - Does your storage tank also have a means for boosting tank temps on cloudy days? Either an electric element of a gas flame will work miracles in getting a 65 degree tank back up to the 150 range. In my opinion a secondary heating element on the storage tank is preferable over a secondary tank. Having to circulate water between two tanks not only looses heat - it takes more energy and mechanical equipment A good aquarium heater is an example of a secondary heating element that would fit the bill on a 50 gallon tank system. The more passive the design - the better. I have an electric element on mine, but I am also operating on a stand alone PV system, so boosting the tank on cloudy days is not an option, but on real sunny days when my batteries are fully charged and tank temps are pretty low (below 105) I will redirect my surplus power production to heat the water tank to max temps. Thus a secondary storage of energy is accomplished. If we get a week of clouds and rain - I may not have hot water. We have had to take 60 degree showers before - it is exhilarating to say the least, but we lived. I can count on one hand the times we have had to do it, but it is something anyone living stand alone solar hot water
should expect to do. IMO it is not worth the cost to add an on-demand LP heater to my system to avoid 3-4 cold showers a year. The cost of both the heater and the additional gas storage capacity and usage is just not worth it to me.
4) Can you limit hot water use only to navy showers (2 minutes/2 gallons of water)? I use hot water from a pot on my
wood stove to warm my dish washing water and to warm up my laundry water for really soiled loads. The solar hot water is strictly for bathing. In the summer when sun is plentiful - I might splurge and use some hot water for dishes and dog baths - but that is about it. I treat it like gold.