Welcome to the forums Devin!
Black Walnut hulls* contain a compound called Juglone that can discourage plants from growing via allelopathic characteristics.
Recently, I discovered that if you soak the hulls* you can use the resulting
water slurry to extract and kill asian jumping worms out of the ground (Allegedly, I need to test it).
I hear you can also powder the hulls to make natural stain/ink.
*EDIT - Hulls not shells! Oops!