Once a duck was being persistent about sitting on eggs, we would collect her and the eggs and put her inside an existing dedicated enclosure.
Two person job ideally; 1 grabs the duck, the other moves the eggs to a nice nest pile inside the enclosure, then 1st person adds the duck. Usually she'd go right back to sitting. We'd keep the broody duck locked up til the eggs hatch, or it becomes apparent they won't be hatching; some of the ducks were just not interested in staying on the nest long
enough. Once we'd identified these, we would not let them start to sit; no sense wasting eggs. If two+ went broody near the same time, the known good brooder/mother got all the eggs.
There is some leeway with duck brooding times since they will generally keep sitting after the first duckling emerge; so, even a couple days after starting to brood, warm eggs could be added to bring up the clutch size if the sitting duck isn't producing a large clutch on her own. However, too many eggs, and they won't all stay warm enough. We aimed for 12ish.