It sounds a bit as though you are saying that there are broody hens and non-broody hens. Pretty much any hen can go broody, although some breeds have reputations for being more broody and/or having good mothering instincts.
I have never heard of anyone deciding for the hen that she was going to be broody

Normally, I see
people talking about how to break a hen's broody mood.
When you get a broody hen, you can decide to help her along, by adding eggs to her nest, rather than leaving it to her to fill it up.
Where do you plan on having your brood hens set their clutch? Hauling them around in the portable coop with the rest of their flock does not sound like a recipe for success to me.
Usually broody hens are given some place quiet, protected and isolated for the three weeks they will spend setting. You don't want hens fighting over the nest box when one is sitting on eggs in that nest...