I don't know much about scaffolding boards, but -NEVER- use pressure treated ANYTHING, anywhere near anything your going to eat/drink, yes, because of the chemicals.
Don't do it.
Most timber cut(kilned) wood in raised bed walls tends to last anywhere between 3-15 years, depending on weather, the wood itself(pine/spruce) and water, etc, and if you line the beds with a liner.
A 5iver at 8ft, something that's going to last 5 years plus, that's a fair good deal, depending on how many beds your going to be putting in, anyways. But a quick google search tells me that most of those scaffolding boards are chemically treated too, they're made with construction in mind, and most of them seem to have at least some kind of fire retardant on them.
But an 4x8' bed would could cost you 15 per bed, plus hardware to hold it together. Is there anything commercially available that would cost the same for less the work, for the number of beds your making?
What works even better and often free? Bricks, old used bricks that you could probably salvage for, for free in most places.
Take a look around you, if there's construction going on, you should be able to salvage something off those sites, or find inspiration from other things.
You can use paving stones on their ends, buried to make a bed, but you might need stabilizer posts.
You can use cord wood lengths, post driven like into the ground.
Some people make a box-bed out of a metal sheeting like corrugated roof sheeting.
And some people take a length of corrugated culvert, cut it into shorter lengths to make round garden beds, or cut it length wise to make troughs.
A raised bed is basically a tiny fence, it just has to be sturdier to keep the soil in, especially if your doing bigger beds (and if it's to wet and rainy, not recommended, or you end up with mud-pools).
A friend of mine with virtually dead soil(clay, nothing but) has to resort to using cheap kiddie pools, and edges them around with stone or bamboo edging when he can get it cheaply enough.
Another one has links to the fishing industry, and uses old fish/icy trays. You can usually get them cheap from fisheries because they have defects like cracks or broken handles from use, if not free, good enough for holding dirt in, and look, drainage. My family in the past has grown a fair amount of carrots and onions and beets to great success out of them(until the neighbour pesticide sprayed his yard next door and it wafted over the fence). That being said, plastic totes work for this if you have to, and you just tip the bin over and break apart the soil to get your bounty, then dump your soil into the
compost pile to overwinter, to replenish the soil. This all, of course, depends on how much your trying to produce. We grew less than a half dozen trays to get just enough 'special' vegetables for bottling.
My google search has even turned up a file from a uk gardening group for seniors that discusses raised beds.
http://carryongardening.org.uk/files/documents/How%20to%20build%20raised%20beds%20final_Nov08.pdf